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04/26 木亦辰

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名:叶恒云

别:

学位/职称:博士/教授

主要研究方向:分子基铁电材料、双稳态多功能材料 、稀土功能材料

主要研究成果:

1)设计了一系列的新型分子铁电材料,发现了一些传统无机铁电材料中没有的铁电物理现象,如配位扭曲导致的铁电性、分子马达中的铁电性、顺电-铁电相变过程中的反常旋光变化、介电铁电传感具有分子识别作用等;

2)构建了一系列的多功能铁电材料,如低带宽的半导体分子铁电体、高光伏电压的分子铁电体、高量子产率的发光铁电体等,发现了极轴最多的分子铁电体并组装了薄膜。相关研究工作以通讯作者(或共同通讯作者)或第一作者发表在ScienceNat. Commun.Angew. Chem. Int. Ed.J. Am. Chem. Soc.Adv. Mater.等一流学术期刊上,促进了分子铁电科学的发展。

代表性论文:

(1)Chao Shi, Jia-Jun Ma, Jia-Ying Jiang, Miao-Miao Hua, Qi Xu, Hui Yu, Yi Zhang*, Heng-Yun Ye*, Large Piezoelectric Response in Hybrid Rare-Earth Double Perovskite Relaxor Ferroelectrics, Journal of the American Chemical Society. 2020, 142, 9634−9641.

(2)Chao Shi, Le Ye, Zhi-Xin Gong, Jia-Jun Ma, Qin-Wen Wang, Jia-Ying Jiang, Miao-Miao Hua, Chang-Feng Wang, Hui Yu, Yi Zhang*, Heng-Yun Ye*Two-Dimensional Organic-Inorganic Hybrid Rare-Earth Double Perovskite Ferroelectrics, Journal of the American Chemical Society, 2020, 142, 1, 545-551.

(3)Shi Chao; Yu Hui; Wang, Qin-Wen; Ye Le.; Gong Zhi-Xin; Ma Jia-Jun ;Jiang Jia-Ying; Hua Miao-Miao; Shuai Chi-Jun; Zhang Yi*; Ye Heng-Yun*, Hybrid Organic-Inorganic Antiperovskites. Angew Chem Int Ed Engl. 2020,59,167 –171

(4) Heng-Yun Ye Yuan-Yuan Tang, Peng-Fei Li, Wei-Qiang Liao, Ji-Xing Gao, Xiu-Ni Hua, Hu Cai, Ping-Ping Shi, Yu-Meng You1, Ren-Gen Xiong, Metal-free three-dimensional perovskite ferroelectrics, Science, 361, 2018, 151–155.

(5) Li, Peng-FeiTang, Yuan-YuanWang, Zhong-XiaYe, Heng-Yun(*), You, Yu-MengXiong, Ren-Gen(*)Anomalously rotary polarization discovered in homochiral organic ferroelectricsNature Communications2016.11.23713635.

(6) Qiang PanZhi-Bo LiuYuan-Yuan TangPeng-Fei LiRong-Wei MaRu-Yuan WeiYi ZhangYu-Meng YouHeng-Yun Ye(*)Ren-Gen Xiong(*), A Three-dimensional Molecular Perovskite Ferroelectric: (3-Ammoniopyrrolidinium)RbBr3Journal of the American Chemical Society2017.01.013954–3957.

(7) Ping-Ping ShiYuan-Yuan TangPeng-Fei LiHeng-Yun Ye(*)Ren-Gen Xiong(*)De Novo Discovery of [Hdabco]BF4 Molecular Ferroelectric Thin Film for Nonvolatile Low-Voltage MemoriesJournal of the American Chemical Society2017.01.011391319~1324.

(8) Ye, Heng-YunLi, Shen-HuiZhang, YiZhou, LeiDeng, FengXiong, Ren-Gen(*), Solid State Molecular Dynamic Investigation of An Inclusion Ferroelectric: [(2,6-Diisopropylanilinium)([18]crown-6)]BF4Journal of the American Chemical Society2014.7.1613628):10033~10040.

承担的项目:

1)国家自然科学基金面上项目,21875093,杂化碱金属-卤素钙钛矿体系的铁电性质研究2019/1-2022/1263万元,在研,主持。

2)国家自然科学基金面上项目,21573041,有机-无机杂化的铁电材料的设计及其在光伏和光解水上的应用,2016/1-2019/12,66万元,在研,主持。

3)重大研究计划/培育项目,91222101,一维氢键型铁电体的可控合成,性能及相关理论的研究,2013/01-2015/12, 70万元,已结题,主持。

4)国家自然科学基金面上项目,20973037N-H-–-N氢键型二茂铁衍生物铁电体,2010.01–2012.12, 38万元,已结题,主持。

 

 

 

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姓名:史超

籍贯:山东滕州

学位/职称:工学博士/特聘教授

出生年月:19893

联系方式:15150517670

电子邮箱:shic@jxust.edu.cn

研究方向:稀土铁电配合物、分子基结构相变材料、分子多铁材料

办公地点:江西理工大学南昌校区综合实验楼B409

个人简介:史超,男,主要从事有机无机杂化晶体中介电和铁电转变的研究。其核心工作是探讨在温度作用下相变过程中固相的动态行为机制。利用分子设计理念,建立有机无机杂化模型化合物,研究体系的动态变化和对外界激励的响应,发现新体系和新材料。近5年,申报人以第一作者或通讯作者身份发表科研论文20余篇,其中代表性科研论文包括J. Am. Chem. Soc. (2 )Nat. Commun. (1 )Angew. Chem. Int. Ed. (1 )Mater. Horiz. (1 )Coord. Chem. Rev. (1 )J. Mater. Chem. C. (2 ) Chem. Eur. J. (1 )等。其中,3篇入选ESI高被引论文,1篇入选ESI热点论文。这些研究进一步理解了分子间相互作用、晶体结构、相变之间的关联,且发现新的极性和结构相变体系,为指导目标体系的合成和性能优化奠定了一定的基础。作为课题负责人主持国家自然科学基金面上基金项目和国家自然科学基金青年基金项目以及江西省自然科学基金重点项目各1项。荣获2018年江西省杰出青年称号;入选2022年度 (第二十六批) 江西省主要学科学术和技术带头人培养计划。

 

讲授课程:

本科生课程:有机化学

研究生课程:金属有机化学、材料科学与工程前沿、绿色化学等

 

代表性论文 (其中,为共同一作,*为通讯作者)

  1. Shi, C.; Ma, J.-J.; Jiang, J.-Y.; Hua, M.-M.; Xu, Q.; Yu, H.; Zhang, Y.; Ye, H.-Y.; J. Am. Chem. Soc., 2020, 142, 9634−9641.

  2. Shi, C.; Ye, L.; Gong, Z.-X.; Ma, J.-J.; Wang, Q.-W.; Jiang, J.-Y.; Hua, M.-M.; Wang, C.-F.; Yu, H.; Zhang, Y.; Ye, H.-Y., J. Am. Chem. Soc., 2020, 142, 545−551.

  3. Shi, C.; Yu, H.; Wang, Q.-W.; Ye, L.; Gong, Z.-X.; Ma, J.-J.; Jiang, J.-Y.; Hua, M.-M.; Shuai, C.-J.; Zhang, Y.; Ye, H.-Y.; Angew. Chem. Int. Ed., 2019, 59, 167−171.

  4. Wang, C.-F.; Shi, C.; Zheng, A.-Y.; Wu, Y.-L.; Ye, L.; Wang, N.; Ye, H.-Y.; Ju, M.-G.; Duan, P.-F.; Wang, J.-L.; Zhang, Y.; Mater. Horiz., 2022, 9, 2450−2459.

  5. Shi C.; Han X.-B.; Zhang W.; Coord. Chem. Rev., 2019, 378, 561−576.

  6. Shi C.; Zhang X.; Yu C.-H.; Yao Y.-F.; Zhang W.; Nat. Commun., 2018, 9, 481−489.

  7. Shi C.; Yu C.-H.; Zhang W.; Angew. Chem. Int. Ed., 2016, 55, 5798−5802.

  8. Shi C.; Zhang X.; Cai Y.; Yao Y.-F.; Zhang W.; Angew. Chem., Int. Ed., 2015, 54, 6206−6210.

 

主持承担科研项目及经费:

  1. 国家青年科学面上项目,22175079,具有铁电性的铵-多原子桥联金属杂化化合物的构筑与性质研究,2022/1−2025/1260万元,在研,主持。

  2. 国家青年科学基金项目,21805119,基于XY4型桥联配体有机无机杂化化合物介电性质研究,2019/1−2021/1227.5万元,已结题,主持。

  3. 江西省主要学科学术和技术带头人培养计划,20225BCJ23006,稀土复钙钛矿分子铁电体的构筑和性质研究,2023/1−2025/1250万元,在研,主持。

  4. 江西省自然科学基金杰出青年基金项目,20192ACBL21010,分子基铁电介电材料合成与性质研究,2019/1−2021/1220万元,已结题,主持。

  5. 江西省自然科学基金重点项目,20224ACB204002,具有光、电响应的稀土杂化相变化合物结构与性质研究,2023/1−2026/1220万元,在研,主持。


 



 

 

名:李建荣

别:

学位/职称:博士/副教授(特聘教授)

主要研究方向:分子基铁电材料、金属硫属化合物光催化材料

主要研究成果:

发展了离子热合成晶态金属硫属化物新方法;利用离子液体的特殊稳定作用合成了一系列超大微孔的金属硫属化物和分立结构的金属硫属化物纳米团簇,并重点研究了这些化合物的光催化性能。主持国家自然科学基金青年科学基金项目(结题),青年-面上连续资助项目(结题)、中科院青年创新基金各一项(结题),及福建省自然科学基金面上项目(结题)。作为学术骨干参与多项国家自然科学基金、科技部973项目和中科院重要方向性项目的研究。在包括Angew. Chem. Int. Ed.NanoscaleChem.Commun.Chem. Eur. J. 等刊物上发表SCI论文50余篇,并有多篇论文被选为封面文章;申请中国发明专利9件,其中4项已授权。已培养3名硕士研究生

近三年代表作:

1. Qianqian Hu, Guowei Chen, Yanqi Wang, Jiance Jin, Minting Hao, Jianrong Li*, Xiaoying Huang*, Enhancing photocatalytic H2 evolution on In2S3/mesoporous TiO2 nanocomposites via one-pot microwave-assisted synthesis using ionic liquid, Nanoscale 2020, 12, 12336-12345.

2. Yanqi Wang, Zhipeng Zhu, Zhaofeng Sun, Qianqian Hu*, Jianrong Li*, Jiang Jiang, Xiaoying Huang, Discrete supertetrahedral T5 selenide clusters and their Se/S solid solutions: Ionic-liquid assisted precursor route syntheses and photocatalytic properties Chem. Eur. J. 2020, 26, 1624-1632. (Hot paper)

3. Yanqi Wang, Qianqian Hu, Jiance Jin, Jilong Li, Jianrong Li* and Xiaoying Huang, [Bmmim]6[In10Se16Cl4]∙(MIm)2: An Organic-ligand Free Discrete T3 Cluster for Efficient Hydrogen Evolution under Visible Light Irradiation, Dalton Trans. 2020, 49, 5020–5023. (Hot paper)

4. Minting Hao, Qianqian Hu*, Yuanfei Zhang, Mingbu Luo, Yanqi Wang, Bing Hu, Jianrong Li* and Xiaoying Huang, Soluble supertetrahedral chalcogenido T4 clusters: High stability and enhanced hydrogen evolution activities, Inorg. Chem. 2019, 58, 5126−5133.

5. Xueda Ding, Song Lei, Chengfeng Du*, Zailai Xie, Jianrong Li*, Xiaoying Huang Small-sized CuS nanoparticles/N, S Co-doped rGO composites as the anode materials for high-performance lithium-ion batteries, Adv. Mater. Interfaces 2019, 6, 1900038.(内封面)

6. Xueda Ding, Chengfeng Du*, Jianrong Li*, Xiaoying Huang, FeS2 microspheres wrapped by N-doped rGO from an Fe-based ionic liquid precursor for rechargeable lithium ion batteries, Sustain. Energ. Fuels 2019, 3, 701-708.(后封面,Hot Paper

7. Nan-Nan Shen, Min-Lan Cai, Ying Song, Ze-Ping Wang, Fu-Quan Huang, Jian-Rong Li,* Xiao-Ying Huang* “Supramolecular organization of [TeCl6]2− with ionic liquid cations: Studies on the electrical conductivity and luminescent properties” Inorg. Chem. 2018, 57, 5282-5291.

8. Nan-Nan Shen, Bing Hu, Chu-Chu Cheng, Guo-Dong Zou, Qian-Qian Hu, Cheng-Feng Du, Jian-Rong Li*, Xiao-Ying Huang*, Discrete supertetrahedral T3 InQ clusters (Q = S, S/Se, Se, Se/Te): Ionothermal syntheses and tunable optical and photodegradation properties, Cryst. Growth Des. 2018, 18, 962-968.

9. Dan-Dan Yang, Wei Li, Wei-Wei Xiong*, Jian-Rong Li,* Xiao-Ying Huang, Ionothermal synthesis of discrete supertetrahedral Tn (n = 4, 5) clusters with tunable components, band Gaps, and fluorescence properties, Dalton Trans. 2018, 47, 5977-5984.后封面)

10. Xue-Da Ding, Nan-Nan Shen*, Jian-Rong Li* and Xiao-Ying Huang “Transition metal-containing ionic liquid crystals with 1-decyl-2,3-dimethylimidazolium: Facile syntheses, crystal structures, thermal properties and NH3 detection” ChemistrySelect 2018, 3, 3731-3736.

授权专利:

1. 李建荣,黄小荥,专利名称一种新型除铯微孔材料银-锡硒化物的制备方法及用途专利号:ZL 200910112276.8,专利申请日期:2009.7.29,专利授权日期:2013.11.13

2. 王泽平,李建荣,黄小荥,专利名称一类锑基荧光材料及其制备方法专利号:ZL 201410424241.9,专利申请日期:2014.8.28,专利授权日期:2016.07.06.

3. 杜乘风,李建荣,黄小荥,专利名称纳米二硒化锡/石墨烯复合材料、其制备方法及应用专利号:ZL 201510775894.6,专利申请日期:2015.11.13,专利授权日期:2017.12.15

4. 戚兴辉,杜克钊,冯美玲,李建荣,黄小荥,专利名称一种用于分离和/或提取稀土元素的离子交换剂专利号:ZL 201510500375.9,专利申请日期:2015.08.14,专利授权日期:2018.2.16

主持科研项目

1. 江西理工大学“学术骨干”启动基金,总金额55.0万,执行年限,2020.5-2023.4,在研。

2. 国家自然科学基金青年-面上连续资助项目,异金属硫属化物光催化材料的离子热合成与性能研究,批准号:21371001,总金额80.0万,执行年限,2014.1-2017.12,已结题。

3. 国家自然科学基金青年基金项目,离子液体中新颖晶态金属硫属化物合成新途径的探索性研究,批准号:21001104,总金额19.0万,执行年限,2011.1-2013.12,已结题。

4. 福建省自然科学基金面上项目,批准号:2016J01083异金属硫属基介孔材料的离子热合成及性能研究 2016.04-2019.03,总金额6.0万,已结题。

5. 中国科学院知识创新工程青年人才领域前沿项目,基于窄带隙硫属化物的有机-无机杂化纳米结构,总金额4.0万,执行年限,2008.1-2010.12,已结题。

姓名:胡兆波

性别:

学位/职称:博士/副研究员

主要研究方向:从事分子基磁性材料、分子基铁电材料、光磁、光电和磁电耦合等多功能材料的设计与性能研究。相关成果以第一作者在J. Am. Chem. Soc.Inorg. Chem.SCI期刊上发表学术论文10余篇

邮箱huzhaobo@jxust.edu.cn

主持科研项目:

1)主持国家自然科学基金青年项目1项:基于磁致伸缩的分子基铁电体设计合成及磁电耦合研究(22105089);2022.01-2024.12
        2)主持江西省自然科学基金青年基金项目1项:光控稀土单分子磁体中的弛豫过程(20224BAB214005);2023.01-2025.12


代表性论文

1. Zhao-Bo Hu, Zhao-Yang Jing, Miao-Miao Li, Lei Yin, Yan-Dong Gao, Fei Yu, Tuo-Ping Hu, Zhenxing Wang, and You Song. Important Role of Intermolecular Interaction in Cobalt(II) Single-Ion Magnet from Single Slow Relaxation to Double Slow Relaxation. Inorg. Chem., 2018, 57, 10761.

2. Xi-Ming Luo,# Zhao-Bo Hu,# Qing-fang Lin, Weiwei Cheng, Jia-Peng Cao, Chen-Hui Cui, Hua Mei, You Song, and Yan Xu. Exploring the Performance Improvement of Magnetocaloric Effect Based Gd-Exclusive Cluster Gd60. J. Am. Chem. Soc., 2018, 140, 11219.#:共同一作)

3. Chao Chen,# Zhaobo Hu,# Jing Li, Huapeng Ruan, Yue Zhao, Gengwen Tan, You Song and Xinping Wang. Isolable Lanthanide Metal Complexes of a Phosphorus-Centered Radical. Inorg. Chem. 2020, 59, 4, 2111. #:共同一作)

4. Han-Yue Zhang,# Chun-Li Hu,# Zhao-Bo Hu,# Jiang-Gao Mao, You Song, and Ren-Gen Xiong. Narrow Band Gap Observed in a Molecular Ferroelastic: Ferrocenium Tetrachloroferrate. J. Am. Chem. Soc. 2020, 142, 3240. #:共同一作)

5. Zhao-Bo Hu, Xin Feng, Jing Li, Yi-Quan Zhang, Lei Yin, Zhenxing Wang, Zhongwen Ouyang, Mohamedally Kurmoo, You Song. Optimal diamagnetic dilution concentration for suppressing dipole-dipole interaction in single-ion magnets. Dalton Trans., 2020, 49, 2159.

6. Chao Chen,# Zhao-Bo Hu,# Huapeng Ruan, Yue Zhao, Yi-Quan Zhang, Gengwen Tan,You Song and Xinping Wang. Tuning the Single-Molecule Magnetism of Dysprosium Complexes by a Redox-Noninnocent Diborane Ligand. Organometallics 2020, 39, 4143. #:共同一作)

7. Zhaobo Hu,# Huancheng Hu,# Zilu Chen, Dongcheng Liu, Yiquan Zhang, Junliang Sun, Yuning Liang, Di Yao, and Fupei Liang. Guest-Induced Switching of a Molecule-Based Magnet in a 3d−4f Heterometallic Cluster-Based Chain Structure. Inorg. Chem. 2021, 60, 633. #:共同一作)

8. Zilu Chen, Zhaobo Hu, Yisheng Li, Yuning Liang, Xinyu Wang, Li Ouyang, Qin Zhao, Haiyan Cheng and Fupei Liang. Manganese clusters of aromatic oximes: synthesis, structure and magnetic properties. Dalton Trans., 2016, 45, 15634. (导师一作)

9. Shaomin Pei,# Zhaobo Hu,# Zilu Chen, Shui Yu, Bo Li, Yuning Liang, Dongcheng Liu, Di Yao and Fupei Liang. Heterometallic hexanuclear Ni4M2 (M = Dy, Y) complexes: structure and single-molecule magnet for the Dy(III) derivative. Dalton Trans., 2018, 47, 1801. #:共同一作)

 

姓名:刘浪

学位/职称:博士/讲师

主要研究方向:钙钛矿材料,光电探测器

邮箱:amn716@163.com

代表性论文:

1. Lang Liu§, Yang Bai§, Xiao Zhang, Yuequn Shang, Chenyue Wang, Hao Wang, Cheng Zhu, Chen Hu, Jiafeng Wu, Yujing Li, Shihe Yang, Zhijun Ning, Huanping Zhou, Qi Chen*. Cation diffusion guides hybrid halide perovskite crystallization during gel stage [J]. Angewandte Chemie International Edition, 2020, 59(15): 5979-5987.

2. Lang Liu, Sheng Huang, Yue Lu, Pengfei Liu, Yizhou Zhao, Congbo Shi, Siyu Zhang, Jiafeng Wu, Haizheng Zhong, Manling Sui, Huanping Zhou, Haibo Jin, Yujing Li,* and Qi Chen*. GrainBoundary Patchesby In Situ Conversion to Enhance Perovskite Solar Cells Stability [J]. Advanced Materials, 2018, 30(29): 1800544.

3. Lang Liu, Hua Zhang, Shuwu Liu, Haimin Yao, Haoqing Hou, Shuiliang Chen*. Hollow carbon nanosphere embedded with ultrafine Fe3O4 nanoparticles as high performance Li-ion battery anode [J]. Electrochimica Acta, 2016, 219: 356-362.

4. Jia-Wen Xiao, Lang Liu, Deliang Zhang, Nicholas De Marco, Jin-Wook Lee, Oliver Lin, Qi Chen,* and Yang Yang*. The emergence of the mixed perovskites and their applications as solar cells [J]. Advanced Energy Materials, 2017, 7(20): 1700491.

姓名:缪乐平

学位:博士

主要研究方向:有机-无机杂化分子材料光、电性质研究与器件应用

邮箱:miaoleping@jxust.edu.cn

近期代表性论文:

[1] Le-Ping Miao, et al, Direct observation of geometric and sliding ferroelectricity in an amphidynamic crystal, Nature Materials, 2022, 21: 1158-1164.

[2] Chang-Feng Wang, et al, Le-Ping Miao, NH4+/K+-substitution-induced C–F–K coordination bonds for designing the highest-temperature hybrid halide double 

perovskite ferroelastic, Chinese Chemical Letters, 2023, 34, 107774.

[3] Na Wang, et al, Le-Ping Miao, Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement 

type hybrid perovskite system, Chinese Chemical Letters, 2024, 35, 108696.

[4] Wang Luo, et al, Le-Ping Miao, Fast rotating dipole array inducing large dielectric response in a RuddlesdenPopper hybrid perovskite ferroelastic, 

Inorganic Chemistry Frontiers, 2023, 10, 5082-5088.

[5] Ze-Jiang Xu, et al, Le-Ping Miao, Crystal Sponge Behavior in a Two-Dimensional Rare-Earth Hybrid Coordinate Polymer, Inorganic Chemistry, 2023, 62, 

13937-13942.

[6] Wang Luo, et al, Le-Ping Miao H/F Substitution Induced Enhancement of Phase Transition Temperature and Quantum Yield in Rare-Earth Hybrid Perovskite, 

Crystal Growth & Design, 2023 23, 465-472.

[7] Wang Luo, et al, Le-Ping Miao, and Na Wang Halogen-Regulated Tc and X-ray Radiation Detection in 2D Hybrid Perovskite Ferroelastic Semiconductor, 

Inorganic Chemistry, 2024 63, 3913-3920.

[8]Na Wang, et al, Le-Ping Miao,Large Enhancement of Polarization in a Layered Hybrid Perovskite Ferroelectric Semiconductor via Molecular Engineering,

Small 2023, 2306502.


主持科研项目:

1. 国家自然科学基金青年项目,22205087,稀土分子转子铁电体的设计合成与性质研究,2023/01-2025/1230万,主持

2. 江西省教育厅一般项目,GJJ210812,基于稀土有机-无机杂化化合物结构相变与性质研究,2022/01-2025/123万,主持





 

 

 

 

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